In
chemistry,
yield, also referred to as
reaction yield, is the
amount of
product obtained in a
chemical reaction. The
absolute yield can be given as the weight in
grams or in
moles (
molar yield). The
percentage yield (or
fractional yield or
relative yield), which serves to measure the effectiveness of a
synthetic procedure, is calculated by dividing the amount of the desired product obtained by the
theoretical yield (the unit of measure for both must be the same):
The theoretical yield is the amount predicted by a
stoichiometric calculation based on the number of moles of all reactants present. This calculation assumes that only one reaction occurs and that the
limiting reactant reacts completely. However the actual yield is very often smaller (the percent yield is less than 100%) for several reasons:
- Many reactions are incomplete and the reactants are not completely converted to products. If a reverse reaction occurs, the final state contains both reactants and products in a state of chemical equilibrium.
- Two or more reactions may occur simultaneously, so that some reactant is converted to undesired by-products.
- Losses occur in the separation and purification of the desired product from the reaction mixture.
- Impurities are present which do not react