Hexaferrum and
epsilon iron (e-Fe) are
synonyms for the
hexagonal close-packed (HCP) phase of
iron that is stable only at extremely high pressure. Takahashi and Bassett at the
University of Rochester mixed 99.8% pure a-iron powder with
sodium chloride, and pressed a 0.5-mm diameter pellet between the flat faces of two diamond anvils. The deformation of the NaCl lattice, as measured by
x-ray diffraction (XRD), served as a pressure indicator. At a pressure of 130 kbar (13 GPa) and room temperature, the
body-centered cubic (BCC)
ferrite powder transformed to the HCP phase in Figure 1. When the pressure was lowered, e-Fe transformed back to ferrite (a-Fe) rapidly. A
specific volume change of -0.20 cm
3/mole ± 0.03 was measured. Hexaferrum, much like
austenite, is more dense than ferrite at the phase boundary. A
shock wave experiment confirmed the diamond anvil results.
Epsilon was chosen for the new phase to correspond with the HCP form of
cobalt.