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Additional
Hyperconjugation
English Wikipedia - The Free Encyclopedia
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Hyperconjugation
In
organic chemistry
,
hyperconjugation
is the interaction of the
electrons
in a
sigma bond
(usually C–H or C–C) with an adjacent empty (or partially filled) non-bonding
p-orbital
,
antibonding
s or
p orbital
, or filled p orbital, to give an extended
molecular orbital
that increases the stability of the system. Only electrons in bonds that are
ß to the positively charged carbon
can stabilize a
carbocation
by hyperconjugation.
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