In
electrochemistry, the
Nernst equation is an equation that relates the
reduction potential of a
half-cell (or the total
voltage, i.e. the
electromotive force, of the
full cell) at any point in time to the
standard electrode potential,
temperature,
activity, and
reaction quotient of the underlying reactions and species used. When the reaction quotient is equal to the equilibrium constant of the reaction for a given temperature, i.e. when the concentration of species are at their equilibrium values, the Nernst equation gives the equilibrium voltage of the half-cell (or the full cell), which is zero; at equilibrium, Q=K, ΔG=0, and therefore, E=0. It is named after the German physical chemist who first formulated it,
Walther Nernst.